SC111 Molecular Geometry Lab
3D Answer Key

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Formula
I
Lewis Structure
II
Reso- 
nance
III
Number of Bonded Atoms
(number of atoms to which central atom is bonded.)
IV
Number of Lone Pairs
(on central atom)
V
Overall Arrangement of the Charge Clouds
(lone pairs + bonded atoms)
These Rotate!
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VI
Geometry of  Atoms
These Rotate!
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VII
Bond Angles
(around central atom)
VIII
Hybrid- 
ization
IX
Bonds 
Sigma/Pi
(total number in structure)
CN-
No
N/A N/A
(lone pairs shown in pink)
Linear
N/A
sp
1 sigma 
2 pi

 CO2
Yes
2
0
2 charge clouds
Linear
180
sp
2 sigma 
2 pi

 NO2-
Yes
2
1
3 charge clouds
(lone pair shown in pink)
 
Bent
ONO is less than 
120
sp2
2 sigma 
1 pi
 SO2
Yes
2
1
3 charge clouds
(lone pair shown in pink)
Bent
OSO is less than 120
sp2
2 sigma 
1 pi
CO32-
Yes
3
0
3 charge clouds
Trigonal Planar
120
sp2
3 sigma 
1 pi
BCl3
No
3
0
3 charge clouds
Trigonal Planar
120
sp2
3 sigma
SO42-
Note: There are four resonance structures of the type on the right.
Yes
4
0
4 charge clouds
Tetrahedral
109.5
sp3
4 sigma 
0 pi 

or

4 sigma 
2 pi 

CH3Cl
No
4
0
4 charge clouds
Tetrahedral
(slightly distorted from a perfect tetrahedral)
~109.5
sp3
4 sigma
NH3
No
3
1
4 charge clouds
(lone pair shown in pink)

Trigonal Pyramidal
<109.5
sp3
3 sigma
PCl5
No
5
0

5 charge clouds

Trigonal Bipyramidal
120, 90, & 180
sp3d
5 sigma
SF6
No
6
0

6 charge clouds

Octahedral
90 and 
180
sp3d2
6 sigma
Formula
Lewis Structure
Reso- 
nance
Number of Bonds Number of Lone Pairs
Overall Arrangement of the Charge Clouds
(lone pairs + bonded atoms)
Geometry of  Atoms
Bond Angles
Hybrid- 
ization
Bonds 
Sigma/Pi
(total number in structure)
Part B: More Complex Molecules

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